Synthesis of (NHC)Pd(salicylaldimine)Cl complexes through template-directed ortho-aromatic metaloxylation of NHC-palladacycles derived from arylimines.

نویسنده

  • Jin Yang
چکیده

Reactions of imidazoliums with palladacycles afforded NHC-palladacycle complexes. The reactivity of the NHC-palladacycles was explored and the results demonstrated that they could be template-directed ortho-aromatic metaloxylated in the presence of tert-butyl hydroperoxide (TBHP), affording (NHC)Pd(salicylaldimine)Cl complexes. Furthermore, the NHC-palladacycles showed efficient catalytic activities toward the ortho-aromatic hydroxylation of arylimines.

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عنوان ژورنال:
  • Dalton transactions

دوره 46 15  شماره 

صفحات  -

تاریخ انتشار 2017